well even a new factory barrels are not perfect. That is polished or as its known hand lapped to bring the inside of the barrel to a mirror finish. yes without a bore scope it would be hard to see inside, a Dr. might have access to one
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for .22 the width should not be more then 5mm. failing that a light shone at one end might show some thing
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look for anything that does not resemble a mirror finish. ie scratches and rough rifling etc